Monday, October 24, 2016

REACTIONS OF POLYMERS



ADDITION POLYMERIZATION
  • A chemical process in which monomers with multiple bonds are joined together by covalent bond to form larger molecule without the loss of a small molecule.
  • Also called Chain-Growth Polymerization.
  • Reactive intermediates at chain end and initiator is needed in this reaction.
  • Some of the examples :

  • Mechanism involved :


CONDENSATION POLYMERIZATION
  •  A chemical process in which two monomers joined together to form larger molecule and eliminate smaller molecule such as H2O, HCL or alcohols (methanol).
  • Also called Step-Growth Polymerization.
  • One of the example :


  • Mechanism involved :



  • COMPARISON BETWEEN ADDITION (CHAIN) & CONDENSATION (STEP) POLYMERIZATION


    To make polymer become more attractive, lets take a look  one of the interesting video :



    Is Polymer Dangerous?


    “Polymer” is not a chemical, but rather a term for a very large covalent molecule made up of many repeating units. Human body also contains many natural polymers; starch, proteins and DNA.


    A vast majority of polymers are safe, and even most artificial polymers, such as polyethylene (one of the simplest) is safe. 


    Most polymers are stable so the main problem is there is nothing on earth to break them down again when thrown away, causing problems with disposal of polymer materials. 

     
    Polyethylene and polyproplyne are not biodegradable. This means that micro-organisms cannot break them down, so they may last for many years in rubbish dumps.

    Some manmade polymers have been questioned not the polymer itself, but chemicals liberated from them over time or when burned. Some of its phthalate plasticisers are believed to mimic human hormones, its constituent monomers are carcinogenic, and it has been blamed for some dioxin formation 
                                               when incinerated.

    Why Is Dangerous To Burn Polymers?

    This is because the dangerous gases that form from polymers in the burning process. When polymers such as plastics are burned carbon containing gases are released.
    During the burning process, the carbon combines with oxygen present in the atmosphere & form oxides of carbon. These gases have been linked global warning, depletion of ozone layer, acid rain and etc.




    They create harmful effects on our ecosystem. It depends what type of polymer it is.

    •   Polyethylene or polypropylene, the gases generated are CO2 and H2O (not dangerous)
    •  Perfluorooctanoic acid (PFOA) is a likely human carcinogen, endocrine-disrupting chemical and reproductive toxin used in the manufacture of fluoropolymers such as DuPont’s Teflon.
    • Perfluorooctanesulfonic acid (PFOS) is a persistent, bioaccumulative, cancer-causing chemical used in Scotchgard. 

    Sunday, October 23, 2016

    HOW ARE POLYMER FORMED?


    • Polymerisation is a process where chemical groups are lost from molecule to bond covalently and occurs through variety of reaction and mechanisms.



    • For instance,compounds such as polyethene and polyvinyl chloride are formed from alkenes.
    • This includes 3 steps of initiation, propagation, termination.

    Application of Polymer


    Daily Uses of Polymer


    Most common types of synthetic organic polymers found in households: 

    • POLY(VINYL CHLORIDE)
    PVC is a thermoplastic made of 57% chlorine (derived from industrial grade salt) and 43% carbon (derived predominantly from oil / gas via ethylene).

                    Image result for pvc
    PVC Hose
    Image result for pvc
    PVC Fitting
    Image result for pvc
    PVC Pipe
    • SUPER ABSORBENT POLYMER
    Super absorbent polymers (SAPs) (also called slush powder) are polymers that can absorb and retain extremely large amounts of a liquid relative to their own mass.
    Image result for what is super absorbent polymer
    Water Beads
    Image result for what is super absorbent polymer
    SAPs in Diapers
    • POLYSTYRENE
    Polystyrene is an inexpensive and hard plastic, and probably only polyethylene is more common in your everyday life.

    Image result for packaging polystyrene
    Packaging
    Image result for appliances polystyrene
    Appliances
    Image result for construction polystyrene
    Construction
    • NYLON  
    a tough, lightweight, elastic synthetic polymer with a proteinlike chemical structure, able to be produced as filaments, sheets, or molded objects.

                                              Image result for nylon 6 10 uses  
    • POLYTETRAFLUOROETHYLENE(TEFLON)              
    Polytetrafluoroethylene is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. The best known brand name of PTFE-based formulas is Teflon by Chemours.

                 Image result for teflon pan
    Cooking Pan

    Image result for teflon
    Teflon Tape
    • POLYPROPYLENE                                                                                                                       
    Polypropylene (PP) is a thermoplastic “addition polymer” made from the combination of propylene monomers. It is used in a variety of applications to include packaging for consumer products, plastic parts for various industries including the automotive industry, special devices like living hinges and textiles.

    Image result for polypropylene
    Rope
    Image result for polypropylene
    Plastic
    Image result for polypropylene
        Side Chair

                 
                                                

    Friday, October 21, 2016

    Classification of Polymer

    Classification of Polymer based on Structure


    • Linear Polymers - A long chain of skeletal atoms to which are attached the substituent group.
    • Branched Polymers - Linear polymer with branches with same structure/polymer as the main chain (1 kind of polymer)
    • Crosslinked/network Polymers - Chemical linkage exist between polymer chain
                 
    • Star Polymers - Have arm radiating from a common core

    • Copolymers - Made from 2 or more different monomer units. Have 4 sequencing arrangements:
    1. Alternating copolymers - Contain a regular alternating sequence of two monomer units
    2. Random copolymers - No definite sequence of monomers units exists
    3. Block copolymers - Diblock, triblock, multiblock
    4. Graft copolymers - Comprises 2 different polymers (a backbone species and a side chain species)